Tris(dibenzylideneacetone)dipalladium(0)

Tris(dibenzylideneacetone)dipalladium(0)

Chembox new
ImageFile = Pd2(dba)3.png ImageSize =
ImageFile1 = Tris(dibenzylideneacetone)dipalladium(0)-3D-balls.png IUPACName = Tris(dibenzylideneacetone)dipalladium
OtherNames = Pd2(dba)3
Section1 = Chembox Identifiers
CASNo = 51364-51-3
PubChem =
SMILES =

Section2 = Chembox Properties
Formula = C51H42O3Pd2
MolarMass = 915.7 g/mol
Appearance =
Density =
MeltingPt = 152 -155 °C
BoilingPt =
Solubility =

Section3 = Chembox Hazards
MainHazards =
FlashPt =
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Tris(dibenzylideneacetone)dipalladium(0)) or Pd2(dba)3 is an organometallic catalyst based on palladium and dibenzylideneacetone used in organic chemistry.

It is prepared by adding hot sodium acetate to a hot methanol solution of dibenzylideneacetone and sodium hexachloropalladate ["Encyclopedia of Reagents for Organic Synthesis", L.A. Paquette, Ed.: J. Wiley and Sons: Sussex, England, 1996]

Examples of reactions using this reagent are the Negishi coupling, Carroll rearrangement and Trost asymmetric allylic alkylation. Another zerovalent palladium catalyst is tetrakis(triphenylphosphine)palladium(0)

External links

- [http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/328774 Datasheet commercial supplier]

References


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