- Triethanolamine
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ImageFile = Triethanolamine.png
ImageSize =
IUPACName = 2,2',2"-Nitrilotriethanol
OtherNames = Tris(2-hydroxyethyl)amine, 2,2',2"-Trihydroxy-triethylamine, Triethylolamine, Trolamine, TEA
Section1 = Chembox Identifiers
CASNo = 102-71-6
EINECS = 203-049-8
PubChem = 7618
SMILES = OCC [N] (CCO)CCO
InChI = 1/C6H15NO3/c8-4-1-7(2-5-9)3-6-10/h8-10H,1-6H2
RTECS = KL9275000
ChEBI = 28621
KEGG = C06771
Section2 = Chembox Properties
Formula = C6H15NO3
MolarMass = 149.188 g/mol
Appearance = Pale yellow liquid,hygroscopic
Density = 1.126 g/cm3
MeltingPt = 20.5°C (293.65 K)
BoilingPt = 208 °C (20 hPa)
335.4°C (608.55 K)
Solubility = Miscible
VapourPressure = 0.01 hPa (20 °C)
Section3 = Chembox Hazards
ExternalMSDS = [http://ptcl.chem.ox.ac.uk/MSDS/TR/triethanolamine.html Oxford MSDS]
MainHazards = Irritant
FlashPt = 179 °C
Autoignition = 325 °C
ExploLimits = 3.6 - 7.2 %
NFPA-H = 2
NFPA-F = 1
NFPA-R =
NFPA-O =
RPhrases = R36, R37, R38
SPhrases = S26, S36Triethanolamine, often abbreviated as TEA, is an
organic chemical compound which is both a tertiaryamine and a tri-alcohol . A tri-alcohol is amolecule with threehydroxyl groups. Like other amines, triethanolamine acts as aweak base due to thelone pair of electrons on thenitrogen atom .Production
Triethanolamine is produced by reacting
ethylene oxide with aqueousammonia ; the reaction also producesmonoethanolamine anddiethanolamine . The ratio of the products can be controlled by changing the stoichiometry of the reactants.cite book | title = Industrial Organic Chemistry | author = Klaus Weissermel, Hans-Jürgen Arpe, Charlet R. Lindley, Stephen Hawkins | publisher =Wiley-VCH | year = 2003 | isbn = 3527305785 | pages = 159-161 | chapter = Chap. 7. Oxidation Products of Ethylene]:
Applications
This ingredient is used as a pH balancer in cosmetic preparations in a variety of different products - ranging from skin lotion, eye gels, moisturizers, shampoos, shaving foams etc.
Another common use of TEA is as a complexing agent for aluminium ions in aqueous solutions. This reaction is often used to mask such ions before performing what is called a
complexometric titration with another chelating agent such asEDTA (EthyleneDiamineTetraAcetic acid), which will form stable complexes with most metallic ions.Triethanolamine (TEA) is also used as organic additive (0.1 wt. %) in the grinding of cement clinker. It is proved to be very effective to facilitate the grinding process by preventing agglomeration and coating of the powder at the surface of balls and mill wall. [Cite journal
last = Sohoni
first = S.
coauthors = R. Sridhar, G. Mandal
date = 1991
title = Effect of grinding aids on the fine grinding of limestone, quartz and portland cement clinker
journal = Powder Technology
volume = 67
issue = 3
pages = 277–286
doi = 10.1016/0032-5910(91)80109-V] To what extent could TEA complex heavy metals andradionuclide s encapsulated in cement matrix and so could increase theirsolubility remains an open question.TEA is listed under Schedule 3, part B of the
Chemical Weapons Convention as it can be used in the manufacture ofnitrogen mustard s.afety
As with any amines, it may have the potential to create
nitrosamines , but with the low concentrations used in cosmetic products the chances of that happening is very slim and it is further theorized that nitrosamines cannot penetrate the skin. Fact|date=April 2007References
ee also
*
Complexometric titration
*Diethanolamine
*Ethanolamine
*Ethanol
*Triethylamine
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